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Journal Articles

Chemical species of iodine during sorption by activated carbon; Effects of original chemical species and fulvic acids

Kato, Tomoaki; Kozai, Naofumi; Tanaka, Kazuya; Kaplan, D. I.*; Utsunomiya, Satoshi*; Onuki, Toshihiko

Journal of Nuclear Science and Technology, 59(5), p.580 - 589, 2022/05

 Times Cited Count:4 Percentile:56.94(Nuclear Science & Technology)

This study reports the effect of fulvic acids, which is a natural organic substance generally contained in groundwater, on the oxidation states of radioactive iodine anions (iodide and iodate). Iodide and iodate are contained in the contaminated water of the Fukushima Daiichi Nuclear Power Plant and supposed to be removed by activated carbon (AC) via adsorption. When fulvic acids does not exist in the experimental system, the adsorption of iodide on AC was less than that of iodate and their oxidation states after the adsorption were not changed. When fulvic acids existed, a fraction of the adsorbed iodate was reduced to iodide. This result indicates that the reduction of the adsorbed iodate progresses during the storage of the spent AC.

Journal Articles

Characterization and thermodynamic study of humic acid in deep groundwater at Horonobe, Hokkaido, Japan

Kimuro, Shingo*; Kirishima, Akira*; Nagao, Seiya*; Saito, Takumi*; Amano, Yuki; Miyakawa, Kazuya; Akiyama, Daisuke*; Sato, Nobuaki*

Journal of Nuclear Science and Technology, 55(5), p.503 - 515, 2018/05

 Times Cited Count:7 Percentile:58.07(Nuclear Science & Technology)

no abstracts in English

Journal Articles

Extraction of groundwater humic substances and characterization by synthetic resin

Ueda, Masato; Sakamoto, Yoshiaki*

Genshiryoku Bakkuendo Kenkyu, 12(1-2), p.31 - 39, 2006/03

no abstracts in English

Journal Articles

Influence of humic substances on the $$^{63}$$Ni migration through crushed rock media

Tanaka, Tadao; Sakamoto, Yoshiaki; Mukai, Masayuki; Maeda, Toshikatsu; Nakayama, Shinichi

Radiochimica Acta, 92(9-11), p.725 - 729, 2004/12

 Times Cited Count:1 Percentile:10.03(Chemistry, Inorganic & Nuclear)

Migration experiments of $$^{63}$$Ni for crushed rocks, granite and tuff, were performed under the coexistent condition with a humic acid and a fulvic acid of 0-30 mg/l in concentration, which are Nordic humic substances supplied from International Humic Substance Society. Migration experiments of Ni had been performed by a column system, to investigate migration behavior of Ni through a column packed crushed rock. The Ni concentration in the effluent passed through the column was corresponding to the fractional percentage of Ni complexing with humic substance in influent solution. This result suggests that the Ni complexing with humic substance in influent solution was flowed out from the column without any effective interactions with the rock media. The migration behavior of Ni could be expressed by a migration model taking account of the complexation kinetics of Ni with humic substance in the aqueous phase.

Journal Articles

Data acquisition for predicting radionuclide migration under deep geological environments

Yamaguchi, Tetsuji; Nakayama, Shinichi

JAERI-Conf 2003-018, p.115 - 116, 2003/10

Effective diffusivity was determined for Np(IV) in bentonite material in presence of carbonate and for Pu(IV) in presence of fulvic acid. Adsorption of actinides onto negatively charged mineral surfaces were investigated under conditions that actinides were predominantly present as anionic complex species. The results of this study will reveal behavior of actinides under various geological environments.

Journal Articles

Direct observation of Cm(III)-fulvate species on fulvic acid-montmorillonite hybrid by laser-induced fluorescence spectroscopy

Takahashi, Yoshio*; Kimura, Takaumi; Minai, Yoshitaka*

Geochimica et Cosmochimica Acta, 66(1), p.1 - 12, 2002/01

 Times Cited Count:63 Percentile:73.51(Geochemistry & Geophysics)

no abstracts in English

JAEA Reports

Organic acid dissolving in groundwater in the Mobara gas field

JNC TN8400 2000-030, 17 Pages, 2000/12

JNC-TN8400-2000-030.pdf:0.44MB

As a representative of natural marine groundwater, the author selected pumped water from a Quaternary sedimentary aquifer of the Mobara gas-field in Japan and measured the concentration of total organic carbon (TOC) and of organic acid anions (formic, acetic, lactic, succinic, humic, fulvic, propionic, valeric and butyric acids). The concentration of TOC ranged from 22$$pm$$1 to 24$$pm$$0mg/L. As organic acid anions, only succinic and fulvic acids were detected and each concentration was given to be from 5.8$$pm$$ 0.5 to 8.3$$pm$$0.3 and from 3.3$$pm$$0.2 to 3.5$$pm$$0.2mg/L, respectively. By consideration of the temperature and the [SO$$_{4}$$$$^{2-}$$] of the groundwater, it is inferred that the organic acid has been significantly decomposed by activities of microbes, such as the fermentation process, CH$$_{3}$$COO$$^{-}$$ + H$$_{2}$$O = HCO$$_{3}$$$$^{-}$$ + CH$$_{4}$$.

Journal Articles

The Migration behavior of Np(V) in sandy soil and granite media in the pressence of humic substances

Sakamoto, Yoshiaki; Nagao, Seiya; Ogawa, Hiromichi; Rao, R. R.*

Radiochimica Acta, 88(9-11), p.651 - 656, 2000/09

 Times Cited Count:11 Percentile:59.85(Chemistry, Inorganic & Nuclear)

no abstracts in English

Journal Articles

The Transfer capability of long-lived chernobyl radionuclides from surface soil to river water in dissolved forms

Amano, Hikaru; Matsunaga, Takeshi; Nagao, Seiya; *; Watanabe, Miki*; Ueno, Takashi; Onuma, Yoshikazu*

Organic Geochemistry, 30, p.437 - 442, 1999/00

 Times Cited Count:28 Percentile:52.71(Geochemistry & Geophysics)

no abstracts in English

Journal Articles

Characteristics of the fluorescent substances in the Yodo river system by three-dimensional excitation emission matrix spectroscopy

Suzuki, Yasuhiro*; Nakaguchi, Yuzuru*; Hiraki, Keizo*; Nagao, Seiya; *; *

Chikyu Kagaku, 32, p.21 - 30, 1998/00

no abstracts in English

Journal Articles

Migration behavior of Eu(III) in sandy soil in the presence of dissolved organic materials

Nagao, Seiya; R.R.Rao*; R.W.D.Killey*; J.L.Young*

Radiochimica Acta, 82, p.205 - 211, 1998/00

no abstracts in English

Journal Articles

Spectroscopic properties of fluorescent substances in natural waters, 1

Suzuki, Yasuhiro*; Nagao, Seiya; Nakaguchi, Yuzuru*; Matsunaga, Takeshi; Muraoka, Susumu; Hiraki, Keizo*

Chikyu Kagaku, 31, p.171 - 180, 1997/00

no abstracts in English

Journal Articles

Speciation of radionuclides in soils and surface organic matters sampled around the Chernobyl nuclear power plants

Watanabe, Miki*; Amano, Hikaru; Onuma, Yoshikazu*; Ueno, Takashi; Matsunaga, Takeshi; Yanase, Nobuyuki

Proc. of 4th Int. Conf. on Nucl. and Radiochemistry, 2, 4 Pages, 1996/00

no abstracts in English

JAEA Reports

None

Higashi, Kunio*

PNC TJ1604 92-001, 84 Pages, 1992/03

PNC-TJ1604-92-001.pdf:4.74MB

None

Journal Articles

Destruction of fulvic acid in water by simultaneous use of radiation and ozone

; ; ;

Suido Kyokai Zasshi, 53(4), p.35 - 42, 1984/00

no abstracts in English

Oral presentation

Characterization and determination of thermodynamic quantities of humic acid dissolved in deep groundwater at Horonobe, Hokkaido, Japan, 2

Kimuro, Shingo*; Kirishima, Akira*; Akiyama, Daisuke*; Sato, Nobuaki*; Nagao, Seiya*; Amano, Yuki; Miyakawa, Kazuya; Terashima, Motoki

no journal, , 

no abstracts in English

16 (Records 1-16 displayed on this page)
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